The habits of a molecule depends a lot on that structure. 2 compounds with the same number of atoms deserve to act an extremely differently. Ethanol (left( ceC_2H_5OH ight)) is a clear fluid that has actually a boiling allude of about (79^ exto extC). Dimethylether (left( ceCH_3OCH_3 ight)) has the same number of carbons, hydrogens, and oxygens, but boils in ~ a much reduced temperature (left( -25^ exto extC ight)). The difference lies in the lot of intermolecular communication (strong (ceH)-bonds because that ethanol, weak valve der Waals pressure for the ether).

You are watching: When does a gas behave most ideally

Real and Ideal Gases

An ideal gas is one that adheres to the gas regulations at all conditions of temperature and pressure. To execute so, the gas needs to fully abide by the kinetic-molecular theory. The gas particlesneed to occupy zero volume and theyneed to exhibit no attractive pressures whatsoever toward each other. Due to the fact that neither of those problems can be true, over there is no such point as an ideal gas. A real gas is a gas that does no behave according to the presumptions of the kinetic-molecular theory. Fortunately, at the conditions of temperature and also pressure that are usually encountered in a laboratory, actual gases often tend to behave an extremely much prefer ideal gases.

Under what problems then, execute gases behave the very least ideally? as soon as a gas is placed under high pressure, its molecule are required closer together as the empty space between the particles is diminished. A diminish in the north space means that the presumption that the volume of the particles themselves is negligible is much less valid. As soon as a gas is cooled, the to decrease in kinetic power of the particles causes them to slow down. If the particles are relocating at slow speeds, the attractive forces between them are much more prominent. Another way to watch it is that continued cooling the the gas will at some point turn it right into a liquid and a liquid is definitely not suitable gas anymore (see fluid nitrogen in the figure below). In summary, a real gas deviates many from an ideal gas at short temperatures and also high pressures. Gases are most ideal in ~ high temperature and also low pressure.

Figure (PageIndex1): Nitrogen gas that has been cooled come (77 : extK) has actually turned come a liquid and must it is in stored in a vacuum insulated container to prevent it from swiftly vaporizing. (CC BY-NC; CK-12)

The figure below shows a graph the (fracPVRT) plotted against pressure because that (1 : extmol) of a gas at three various temperatures—(200 : extK), (500 : extK), and also 1000 : extK). An ideal gas would have a worth of 1 because that that ratio at all temperatures and pressures, and the graph would just be a horizontal line. As deserve to be seen, deviations from perfect gas occur. Together the pressure starts to rise, the attractive forces cause the volume of the gas to be less than expected and also the worth of (fracPVRT) drops under 1. Ongoing pressure increase results in the volume the the corpuscle to become far-reaching and the value of (fracPVRT) rises to better than 1. Noticethat the size of the deviations from ideality is greatest for the gas at (200 : extK) and least for the gas in ~ (1000 : extK).

See more: Was I Love Lucy Ever In Color ? 25 Rare Photos Of I Love Lucy In Color

Figure (PageIndex2): real gases deviate from right gases in ~ high pressures and low temperatures. (CC BY-NC; CK-12)

The ideality of a gas likewise depends on the toughness and kind of intermolecular attractive forces that exist in between the particles. Gases whose attractive pressures are weak are much more ideal than those with strong attractive forces. In ~ the same temperature and also pressure, neon is much more ideal than water vapor due to the fact that neon"s atom are only attracted by weak dispersion forces, while water vapor"s molecules are attracted by fairly stronghydrogen bonds. Helium is a much more ideal gas 보다 neon since its smaller number of electrons means that helium"s dispersion forces are also weaker than those of neon.